Just want to clarify:
We say “a las cuatro de la tarde”.
Are there any other prepositions that we use with specific times?
When you're specifying the part of the day of a specific time, as in "is it at 4 in the morning or at 4 in the afternoon?" we always use the preposition "de". It'd be incorrect or very odd to say for example "El vuelo sale a las cuatro en/por/a la mañana/tarde." (The flight is at 4 AM/PM)
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